Dmitry Perekalin @DmitryPerekalin
Organometallic chemist. Group leader at Nesmeyanov Institute, Russian Academy of Sciences. Make science, not war. dmitryperekalin.blogspot.com Joined September 2013-
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Beware of unexpected effect of amine in 1H NMR. You expect your residual standard signal of CHCl3 to be at 7.26 ppm, but it can actually be shifted for 0.5 ppm due to hydrogen bonding with a strong amine.
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Interesting paper with application 2-pyridones for C-H activation. pubs.acs.org/doi/10.1021/ja…
Nice idea about using iron complexes for curing of oil paints under sunlight. …mistry-europe.onlinelibrary.wiley.com/doi/10.1002/ce…
Dmitry Perekalin retweeted
Waste polystyrene upcycling via the Birch reduction with ball-mill grinding. Out now in Nature Communications! rdcu.be/eujAy
Dmitry Perekalin retweeted
1/ How do insects go green? Not with chlorophyll, but with a protein that mimics it. Meet dibilinoxanthinin (DBXN), a molecular LED built from yolk protein.🧵
Dmitry Perekalin retweeted
Checkout @soumenpaira1 latest @ChemicalScience 🎉 on Chemoselective asymmetric hydrogenation of ketones, ketoesters & β-ketoamides using [Mn–cinchona] catalyst. Thanks @anrfonline for funding, @IITKanpur for infra & @iitbombay (Sunoj) for DFT! 👉 doi.org/10.1039/D5SC02…
Dmitry Perekalin retweeted
White to play! Find a checkmate 🔎 Level: 1800+
Dmitry Perekalin retweeted
Merging azacoronene with helicenes has led to intriguing electroactive chiral structures and polymers. Our latest paper with Yucheng Fu @ycfu1018 and @SwagerGroup just published in @JOC_OL pubs.acs.org/doi/10.1021/ac…
Our new paper on simple synthesis of planar-chiral ruthenium catalysts. We still need to optimize aryl substituent for good enantioselectivity. Thanks to editor and referees of Dalton Transactions for thoughtful and fast reviewing process (only 12 days!). pubs.rsc.org/en/content/art…
Nice paper pubs.acs.org/doi/full/10.10…
Our nitrene insertion into boranes is finally published in Chemical Science. Think about replacing your C-C bonds with fancy B-N bonds :) doi.org/10.1039/D5SC00…
Dmitry Perekalin retweeted
I really happy to share our lastest publication in @J_A_C_S "Generation of Stereocenters via Single-Carbon-Atom Doping Using N-Isocyanides" Huge congrats to everyone involved! And excited to see my first paper as a corresponding author! pubs.acs.org/doi/10.1021/ja…
Dmitry Perekalin retweeted
Recently we have noticed the literature trend and confirmed it together with Prof. Liao's research group through the discovery of one of the most active catalysts for polymerisation of caprolactone doi.org/10.1016/j.eurp…
Dmitry Perekalin retweeted
Super excited to share this *radically* cool work from Deepta, En-Chih, Jeff, and Arunava on a general deaminative cross-coupling method guided by a unique ‘radical sorting’ mechanism. Congrats Team Deamination! Pre-print available now on @ChemRxiv tinyurl.com/bdekw7ds
Dmitry Perekalin retweeted
My first chemistry professor in Vienna, Erich Zbiral, shall not be forgotten. Everybody loves the Tanabe-Eschenmoser Fragmentation but the analogous Zbiral Fragmentation of epoxy vinyl azides is equally cool.
Dmitry Perekalin retweeted
Fluorine substitution for hydrogen increases the stability of organic azides. Our new article in Chem. Commun. and front cover. pubs.rsc.org/en/content/art…
When reading a scientific paper in chemistry (or related fields), how often do you look only at the schemes (without reading the main text)?
Dmitry Perekalin retweeted
best move of 2025
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