Main Group Chemistry @ IISERTVM @MainTvm
We are Synthetic Chemists Interested in the Structure and Reactivity of Main Group Compounds. maingroupchemistrylab.com Joined June 2019-
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Serendipitous Isolation of an Aldehyde Stabilised Alkoxyaluminium Dication - now published in Chemical Communications We thank @ANRFIndia for generously supporting unconventional research in traditional areas of synthetic chemistry! Treating the aluminium diation with Et3SiH…
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Main Group Chemistry @ IISERTVM retweeted
Manjur’s paper on crystallizing and characterizing a boravinylidene is now online in @J_A_C_S. Congrats to @IamMOAkram and our collaborators Kirk French and Kevin Shuford! Check it out here: pubs.acs.org/doi/10.1021/ja…
Main Group Chemistry @ IISERTVM retweeted
Thrilled to share a first publication of the group! We report on cadmium aluminyls that find application as Cd-nucleophiles and(!) Al(I)-Transfer reagents. Now out in @J_A_C_S ! Thanks to @chemieverband for the generous funding of our research. pubs.acs.org/doi/10.1021/ja…
Main Group Chemistry @ IISERTVM retweeted
🚨 New Paper Alert! 🚨 Our latest work in ChemComm reports a new class of phenanthroline–squaramide foldamers adopting robust single-helical structures 🧬. Stable even in DMSO & at 85 °C! Kudos to @RenittaBenny & thanks to Alex, @CSIR_IND @tvmiiser pubs.rsc.org/en/content/art…
Main Group Chemistry @ IISERTVM retweeted
Here is our latest work on organochalcogen compounds modulating the chemistry of nitrite. Congratulations, Tuhin! pubs.acs.org/doi/10.1021/ac…
Main Group Chemistry @ IISERTVM retweeted
Here is our latest work showing simple copper(II) salts like CuCl2 are capable of participating in PCET. Congratulations, to the team! …mistry-europe.onlinelibrary.wiley.com/doi/10.1002/ej…
Main Group Chemistry @ IISERTVM retweeted
There are no examples of uranium-antimony multiple bonds, even under spectroscopic scenarios. Until now. Check out our work on U-Sb bonds spanning single, double, and pseudo-triple bonding interactions. Out now in @NatureComms! nature.com/articles/s4146…
Main Group Chemistry @ IISERTVM retweeted
Di-n-Butylcalcium exists! Thrilled to see this work from my previous postdoc published in @ChemistryEur. It was truly a team effort and a fantastic collaboration between @RennesUniv @chimie_ISCR and COBRA (@Labex_SynOrg) …mistry-europe.onlinelibrary.wiley.com/doi/10.1002/ce…
Main Group Chemistry @ IISERTVM retweeted
The aluminyl anion performing as a reducing agent... Reductive Deamination of a Diaminogermylene Promoted by an Aluminyl Anion: Isolation of Ge(I), Ge(0) and Ge(‐I) Products - Angewandte Chemie International Edition (onlinelibrary.wiley.com/doi/10.1002/an…)
Main Group Chemistry @ IISERTVM retweeted
@liampgriffin and I have reviewed recent advances in the heterometallic bonding chemistry of the alkaline earth metals @DaltonTrans. It was fun to put this together, and we hope it's useful! pubs.rsc.org/en/content/art…
Main Group Chemistry @ IISERTVM retweeted
🎊Cheers to fresh milestones! @rr_lab’s first contributions in *ACS Catalysis— A Heartfelt congratulations to Bincy, Anagha & Venkadesh for their hard work and well-deserved Achievement ! 👏 is.gd/PbS2u6 @rr_lab @rr_prof @Chemie_iisertvm @tvmiiser
Main Group Chemistry @ IISERTVM retweeted
Pleased to share Falk’s latest work @Ghadwal_Group on a non-classical germanium diradicaloid, just published in @angew_chem highlighting a new approach (using anionic dicarbenes) to main-group diradicaloids: onlinelibrary.wiley.com/doi/10.1002/an… #maingroup #diradicals thanks to @dfg_public
Isostructural Mg and Zn compounds: analogies and differences in reactivity - now published in Dalton Transactions pubs.rsc.org/en/content/art…
Main Group Chemistry @ IISERTVM retweeted
Excited to share @D4vdNdrson latest work, just accepted @angew_chem on the structure and applications of #sodium #neopentyl a donor free #organosodium reagent soluble in #hydrocarbon solvents @DCBPunibern #OpenAccess onlinelibrary.wiley.com/doi/epdf/10.10…
Main Group Chemistry @ IISERTVM retweeted
The first of a couple of papers just coming out... Reversible alkyne functionalization at tin! Aidan & Lewis’s study of the reactivity of alkynes with a silyl-stannylene – demonstrating regioselective and reversible insertion – is just out in @ChemEurJ @OxfordChemistry @OxICFM
Main Group Chemistry @ IISERTVM retweeted
Postdoctoral position for anyone proficient in ML (machine learning) or DFT (density functional theory). Submit your application here linkedin.com/posts/rameshra…
Isostructural Mg and Zn Compounds: Analogies and Differences in Reactivity - now published in Dalton Transactions pubs.rsc.org/en/content/art… @kritipathak04 @suban_kundu @skathayat27 @ANRFIndia @tvmiiser #maingroup
Main Group Chemistry @ IISERTVM retweeted
New preprint from @yangwenbang0310 on the synthesis of a novel alumaborane containing an AlH-BH functional group along with some chemoselective reactivity. Here's the link. chemrxiv.org/engage/chemrxi…
Main Group Chemistry @ IISERTVM retweeted
🌞In our new @ChemicalScience work, we track how structural disorder in eumelanin model multimers, from monomer to aggregate, drives nonradiative decay and photoprotection. Kudos to @KavyaVinod19 @DianaThomas01 @maheshhrn! 🎉🥳pubs.rsc.org/en/content/art… @Chemie_iisertvm @tvmiiser
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